The rear/inner seals are available and a common size. I can't find the actual part number for the ones I bought, but the replacements are a standard 2 lipped seal. 5.125" outer, 3.875" shaft and 1/2" thick. I think they were about $15 each.
I am betting that your diff breather is blocked. Pressure built up and pushed the oil past the front seal and into the grease-packed bearings, then pushed the mixed slurry out through the rear seal. I make sure I park with the axles level now, so the oil sits down in the bottom of the diff, not across one side against the hub. Think that's why mine leaked badly a few months after I parked it when I first got it.
Refit the hub, do up the hub nut and the outer nut with seal. Put a straight-edge across the seal lips and the face of the hub between the axle studs. The seal lip should be about 1mm higher. If it doesn't protrude, you could put a spacer between the lock washer and nut with the seal to push it out a bit to make better contact with the inner face of the axle flange.
If the seal on the outer nut looks worn or torn, let me know. I might be able to help. I have a couple of original seals but they are rock hard. I think you are supposed to soften them in oil before use, but didn't want to do that unless I was going to use one.
Actually, a better idea. If you need one, I'll pull the whole nut and seal off the MK3 and send it to you. You can send me yours back once you are going again and I will try out these NOS seals. Let me know if you want to try that.
As for the air pressure issue, the overpressure valve is supposed to release at 150psi, not 120. The valve is very basic, pretty much just a spring and ball bearing. The spring might be getting a bit weak. You could pull it out and stretch it a bit, I suppose.
If you loosen the flare nut on the left side of the tap, (towards the front of the truck), you should get loads of air hissing out. If none, the passage in the tap is clogged. If there is plenty of air, the governor/unloader unit might be carboned up. Page 42 of the MK3 Service manual mentions that. Explains how it all comes apart.
If you need a digital copy of the Workshop manual, grab it here..
International MK3 Service ManualGreg.